Chemistry Class
12 Syllabus
Unit Title
I Solid State
II Solutions
III Electrochemistry
IV Chemical
Kinetics
V Surface
Chemistry
VI Isolation of
Elements
VII p-Block
Elements
VIII d- and f-Block
Elements
IX Coordination
Compounds
X Haloalkanes
and Haloarenes
XI Alcohols,
Phenols and Ethers
XII Aldehydes,
Ketones and Carboxylic Acids
XIII Organic
Compounds containing Nitrogen
XIV Biomolecules
XV Polymers
XVI Chemistry in
Everyday Life
Unit I: Solid State
Classification of solids based on different binding
forces: molecular, ionic, covalent and metallic solids, amorphous and
crystalline solids (elementary idea). Unit cell in two dimensional and three
dimensional lattices, calculation of density of unit cell, packing in solids,
packing efficiency, voids, number of atoms per unit cell in a cubic unit cell,
point defects, electrical and magnetic properties.
Band theory of metals, conductors, semiconductors and
insulators and n & p type semiconductors.
Unit II: Solutions
Types of solutions, expression of concentration of
solutions of solids in liquids, solubility of gases in liquids, solid
solutions, colligative properties - relative lowering of vapour pressure,
Raoult's law, elevation of boiling point, depression of freezing point, osmotic
pressure, determination of molecular masses using colligative properties,
abnormal molecular mass, van't Hoff factor.
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Unit III: Electrochemistry
Redox reactions, conductance in electrolytic solutions,
specific and molar conductivity, variations of conductivity with concentration,
Kohlrausch's Law, electrolysis and law of electrolysis (elementary idea), dry
cell -electrolytic cells and Galvanic cells, lead accumulator, EMF of a cell,
standard electrode potential, Nernst equation and its application to chemical
cells, Relation between Gibbs energy change and emf of a cell, fuel cells,
corrosion.
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Unit IV: Chemical Kinetics
Rate of a reaction (Average and instantaneous), factors
affecting rate of reaction: concentration, temperature, catalyst; order and
molecularity of a reaction, rate law and specific rate constant, integrated
rate equations and half life (only for zero and first order reactions), concept
of collision theory (elementary idea, no mathematical treatment). Activation
energy, Arrhenious equation.
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Unit V: Surface Chemistry
Adsorption - physisorption and chemisorption, factors
affecting adsorption of gases on solids, catalysis, homogenous and heterogenous
activity and selectivity; enzyme catalysis colloidal state distinction between
true solutions, colloids and suspension; lyophilic , lyophobic multimolecular
and macromolecular colloids; properties of colloids; Tyndall effect, Brownian
movement, electrophoresis, coagulation, emulsion - types of emulsions.
Unit VI: General Principles and Processes of Isolation of
Elements
Principles and methods of extraction - concentration,
oxidation, reduction - electrolytic method and refining; occurrence and
principles of extraction of aluminium, copper, zinc and iron.
Unit VII: p - Block Elements
Group 15 Elements: General introduction, electronic
configuration, occurrence, oxidation states, trends in physical and chemical
properties; nitrogen preparation properties & uses ; compounds of nitrogen,
preparation and properties of ammonia and nitric acid, oxides of nitrogen
(Structure only) ; Phosphorus - allotropic forms, compounds of phosphorus:
preparation and properties of phosphine, halides PCl3 , PCl5 and oxoacids
(elementary idea only).
Group 16 Elements: General introduction, electronic
configuration, oxidation states, occurrence, trends in physical and chemical
properties,dioxygen: Preparation, Properties and uses, classification of
oxides, Ozone, Sulphur -allotropic forms; compounds of sulphur: Preparation
properties and uses of sulphur-dioxide, sulphuric acid: industrial process of
manufacture, properties and uses; oxoacids of sulphur (Structures only).
Group 17 Elements: General introduction, electronic
configuration, oxidation states, occurrence, trends in physical and chemical
properties; compounds of halogens, Preparation properties and uses of chlorine
and hydrochloric acid, interhalogen compounds, oxoacids of halogens (structures
only).
Group 18 Elements: General introduction, electronic
configuration, occurrence, trends in physical and chemical properties, uses.
Unit VIII: d and f Block Elements
General introduction, electronic configuration,
occurrence and characteristics of transition metals, general trends in
properties of the first row transition metals - metallic character, ionization
enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic
properties, interstitial compounds, alloy formation, preparation and properties
of K2Cr2O7 and KMnO4.
Lanthanoids - Electronic configuration, oxidation states,
chemical reactvity and lanthanoid contraction and its consequences.
Actinoids - Electronic configuration, oxidation states
and comparison with lanthanoids.
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Unit IX: Coordination Compounds
Coordination compounds - Introduction, ligands,
coordination number, colour, magnetic properties and shapes, IUPAC nomenclature
of mononuclear coordination compounds. Bonding, Werner's theory, VBT, and CFT;
structure and stereo isomerism, importance of coordination compounds (in
qualitative inclusion, extraction of metals and biological system).
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Unit X : Haloalkanes and Haloarenes
Haloalkanes: Nomenclature, nature of C-X bond, physical
and chemical properties, mechanism of substitution reactions, optical rotation.
Haloarenes: Nature of C -X bond, substitution reactions
(Directive influence of halogen in monosubstituted compounds only.
Uses and environmental effects of - dichloromethane,
trichloromethane, tetrachloromethane, iodoform freons, DDT.
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Unit XI: Alcohols, Phenols and Ethers
Alcohols: Nomenclature, methods of preparation, physical
and chemical properties( of primary alcohols only), identification of primary,
secondary and tertiary alcohols, mechanism of dehydration, uses with special
reference to methanol and ethanol.
Phenols: Nomenclature, methods of preparation, physical
and chemical properties, acidic nature of phenol, electrophillic substitution
reactions, uses of phenols.
Ethers: Nomenclature, methods of preparation, physical
and chemical properties, uses.
Unit XII: Aldehydes, Ketones and Carboxylic Acids
Aldehydes and Ketones: Nomenclature, nature of carbonyl
group, methods of preparation, physical and chemical properties, mechanism of
nucleophillic addition, reactivity of alpha hydrogen in aldehydes: uses.
Carboxylic Acids: Nomenclature, acidic nature, methods of
preparation, physical and chemical properties; uses.
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Unit XIII: Organic compounds containing Nitrogen
Amines: Nomenclature, classification, structure, methods
of preparation, physical and chemical properties, uses, identification of
primary, secondary and tertiary amines.
Cyanides and Isocyanides - will be mentioned at relevant
places in context.
Diazonium salts: Preparation, chemical reactions and
importance in synthetic organic chemistry.
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- Organic Compounds Containing Nitrogen 1
- Organic Compounds Containing Nitrogen 2
- Organic Compounds Containing Nitrogen 3
- Organic Compounds Containing Nitrogen 4
- Organic Compounds Containing Nitrogen 5
Unit XIV: Biomolecules
Carbohydrates - Classification (aldoses and ketoses),
monosaccahrides (glucose and fructose), D-L configuration oligosaccharides
(sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen)
importance.
Proteins - Elementary idea of α - amino acids, peptide
bond, polypeptides, proteins, structure of proteins - primary, secondary,
tertiary structure and quaternary structures (qualitative idea only),
denaturation of proteins; enzymes. Hormones - Elementary idea excluding
structure.
Vitamins - Classification and functions.
Nucleic Acids: DNA and RNA.
Unit XV: Polymers
Classification - natural and synthetic, methods of
polymerization (addition and condensation), copolymerization, some important
polymers: natural and synthetic like polythene, nylon polyesters, bakelite,
rubber. Biodegradable and non-biodegradable polymers.
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Unit XVI: Chemistry in Everyday life
Chemicals in medicines - analgesics, tranquilizers
antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics,
antacids, antihistamines.
Chemicals in food - preservations, artificial sweetening
agents, elementary idea of antioxidants.
Cleansing agents - soaps and detergents, cleansing
action.
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CHEMISTRY CLASS XII Practical
Micro chemical methods are available for several of the practical experiments. Wherever possible such techniques should be used.
A.Surface Chemistry
(a) Preparation of one lyophilic and one
lyophobic sol. Lyophilic sol: starch, egg albumin and gum. Lyophobic sol: aluminium hydroxide, ferric hydroxide, arsenious sulphide.
(b) Dialysis ofsol prepared in (a) above.
(c) Study of the role of emulsifying agent in stabilizing the emulsions of different oils.
(b) Dialysis ofsol prepared in (a) above.
(c) Study of the role of emulsifying agent in stabilizing the emulsions of different oils.
B. Chemical Kinetics
(a) Effect of concentration and temperature on the rate of reaction between sodium thiosulphate
and hydrochloric acid.
(b) Study of reaction rates of any one of the following:
(b) Study of reaction rates of any one of the following:
(i) Reaction of iodide ion with hydrogen
peroxide at room temperature using different concentration of iodide ions.
(ii) Reaction between potassium iodate (KIO3) and sodium sulphite (Na2SO3) using starch solution as indicator (clock reaction).
(ii) Reaction between potassium iodate (KIO3) and sodium sulphite (Na2SO3) using starch solution as indicator (clock reaction).
C. Thermochemistry
Any one of the following experiments:
(a) Enthalpy of dissolution of copper sulphate or potassium nitrate.
(b) Enthalpy of neutralization of strong acid (HCl) and strong base (NaOH).
(c) Determination of enthalpy change during interaction (Hydrogen bond formation) between acetone and chloroform.
(a) Enthalpy of dissolution of copper sulphate or potassium nitrate.
(b) Enthalpy of neutralization of strong acid (HCl) and strong base (NaOH).
(c) Determination of enthalpy change during interaction (Hydrogen bond formation) between acetone and chloroform.
D. Electrochemistry
Variation of cell potential in Zn/Zn2+ //Cu2+/Cu with change in concentration of electrolytes (CuSO4 or
ZnSO4) at room temperature.
E. Chromatography
(a) Separation of pigments from extracts of leaves and flowers by paper chromatography
and determination of Rf values.
(b) Separation of constituents present in an
inorganic mixture containing two cations only (constituents having wide difference in R f values
to be provided).
F. Preparation of Inorganic Compounds
(a) Preparation of double salt of ferrous ammonium sulphate or potash alum.
(b) Preparation of potassium ferric oxalate.
G. Preparation of Organic Compounds
Preparation of any one of the following compounds: (a) Acetanilide (b) Di-benzal acetone (c) p-Nitroacetanilide. (d) Aniline yellow or 2-Napththol aniline dye.
H. Test for the Functional Groups Present in Organic Compounds
Unsaturation, alcoholic, phenolic, aldehydic, ketonic, carboxylic and amino (primary) groups.
I. Study of Carbohydrates, Fats and Proteins in Pure Form and Detection of their Presence in given Food Stuffs
J. Determination ofConcentration/Molarity against a Standard Solution of of KMnO4Solution by Titrating it
(a) Oxalic acid (b) Ferrous ammonium sulphate
(Students will be required to prepare standard solutions by weighing
themselves).
K. Qualitative Analysis
Determination of one anion and one cation in a given salt. Cations – Pb2+ ,Cu2+ ,As 3+ ,Al3+ , Fe3+ , Mn2+ , Ni2+ , Zn2+ , Co2+ , Ca2+ , Sr2+ , Ba2+ , Mg2+, NH4+
Anions – CO32–,
S2– , SO32–,
SO4–2,
NO2–, NO3–, Cl–,
Br–, I–, PO3–4 ,
C2O4 –2
(Note : Insoluble salts excluded)
Investigatory Project
Scientific investigations involving laboratory testing and collecting information from
other sources.
A few suggested projects
- Study of presence of oxalate ions in guava fruit at different stages of ripening.
- Study of quantity of casein present in different samples of milk.
- Preparation of soybean milk and its comparison with the natural milk with respect to curd formation, effect of temperature, etc.
- Study of the effect of potassium bisulphate as food preservative under various conditions (temperature, concentration, time etc.)
- Study of digestion of starch by salivary amylase and effect of pH and temperature on it.
- Comparative study of the rate of fermentation of following materials: wheat flour, gram flour, potato juice, carrot juice etc.
- Extraction of essential oils present in Saunf (aniseed), Ajwain (carum), Illaichi (cardamom).
- Study of common food adulterants in fat, oil, butter,sugar, turmeric powder, chilli powder and pepper.
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